When you use a microwave oven to heat water in a glass or glazed container, the water will have difficulty boiling properly. That's because boiling is an accelerated version of evaporation in which water vapor evaporates not only from the water's upper surface, but also through the surface of any water vapor bubbles the water happens to contain. I use the phrase "happens to contain" because that is where all the trouble lies.

Below water's boiling temperature, bubbles of water vapor are unstable—they are quickly crushed by atmospheric pressure and vanish into the liquid. At or above water's boiling temperature, those water vapor bubbles are finally dense enough to withstand atmospheric pressure and they grow via evaporation, rise to the surface, and pop. At that point, I'd probably call the water vapor by its other name: steam. But where do those steam or water vapor bubbles come from in the first place?

Forming water vapor bubbles in the midst of liquid water, a process called nucleation, is surprisingly difficult and it typically happens at hot spots or non-wetted defects (places where the water doesn't completely coat the surface and there is trapped air). When you boil water in a metal pot on the stove, there are hot spots and defects galore and nucleating the bubbles is not a problem. When you boil water in a glass or glazed container using a microwave oven, however, there are no significant hot spots and few non-wetted defects. The water boils fitfully or not at all. The "not at all" possibility can lead to disaster.

Water that's being heated in a metal pot on the stove boils so vigorously that the stove is unable to heat it more than tiny bit above its boiling temperature. All the heat that's flowing into the water is consumed by the process of transforming liquid water into gaseous water, so the water temperature doesn't rise. Water that's being heated in a glass container in a microwave oven boils so fitfully that you can heat it above its boiling temperature. It's simply not able to use up all the thermal energy it receives via the microwaves and its temperature keeps rising. The water becomes superheated.

Most of the time, there are enough defects around to keep the water boiling a bit and it superheats only a small amount. When you remove the container of water from the microwave oven and toss in some coffee powder or a teabag, thus dragging air bubbles below the surface, the superheated water boils into those air bubbles. A stream of bubbles suddenly appears on the surface of the water. Most people would assume that those bubbles had something to do with the powder or teabag, not with the water itself. Make no mistake, however, the water was responsible and those bubbles are mostly steam, not air.

Occasionally, though, the water fails to boil at all or stops boiling after it manages to wet the last of the defects on the glass or glazed surface. I've made this happen deliberately many times and it's simply not that hard to do. It can easily happen by accident. With no bubbles to assist evaporation, the water's only way to get rid of heat is via evaporation from its top surface. If the microwave oven continues to add thermal energy to the water while it is having such difficulty getting rid of that energy, the water's temperature will skyrocket and it will superheat severely.

Highly superheated water is explosive. If something causes nucleation in that water, a significant fraction of the water will flash to steam in the blink of an eye and blast the remaining liquid water everywhere. That boiling-hot water and steam are a major burn hazard and the blast can break the container or blow it across the room. I've heard from a good number of people who have been seriously hurt by exploding superheated water produced accidentally in microwave ovens. It's a hazard people should take seriously.

After that long introduction, it's time to answer your question. Yes, I believe that the microwave makers are responsible for advising people of this hazard. Moreover, they know that they are responsible for doing it. If you look at any modern microwave oven user manual, you will find a discussion of superheating or overheating. Look at your manual, I'll bet it's in there.

But that discussion will almost certainly be buried in the middle of an long list of warnings. For example, in one manual, the discussion of overheated water appears as item 17 of 22, after such entries as "4. Install or locate this appliance only in accordance with the provided installation instructions" and "12. Do not immerse cord or plug in water". To be fair to the manufacturer, warning 17 is longest of the bunch and it suggests mostly reasonable precautions (although I'm not so happy with recommendation 17a: "Do not overheat the liquid."). No Duh.

I think the issue is this: most product warnings are provided not out of any sincere concern for the consumer, but out of fear of litigation. A manufacturer's goal when providing those warnings is therefore to be absolutely comprehensive so that they can point to a line in a user manual in court and claim to have fulfilled their responsibility. The number and order of the warnings makes no difference; they just have to be in there somewhere.

So all those warnings you ignore in product literature aren't really about consumer safety, they're about product liability. You ignore them because everything now comes with a thousand of them, ranging from the reasonable to the ridiculous. For my research, I ordered 99.999% pure sodium chloride (i.e., ultrapure table salt). It came with a 6-page Material Safety Data Sheet that identifies it as an "Xi Irritant", noting that it is "Irritating to eyes, respiratory system and skin" and recommending first aid measures that include:

"After inhalation: supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.
After skin contact: Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.
After eye contact: rinse opened eye for several minutes under running water. Then consult a doctor."

So much for swimming in the ocean...

By design and by accident, our society has lost the ability to distinguish real risk from imaginary risk. We treat all risks as equal and spend way too much time worrying about the wrong ones. If you want to be safer around your cell phone, for example, you should worry more about driving with it in your hand than about the microwave radiation it emits. The current evidence is that your risk of injury or death due to a cell-phone related accident far outweighs your risk from cell-phone microwave exposure. Even if further research proves that cell phone microwave exposure is injurious, we should be acting according to our best current assessments of risk, not according to fears and beliefs.

That said, I'd like to see product literature rank their warnings according to risk and put the real risks in a separate place where they can't be overlooked or ignored. Put the real consumer safety stuff where the consumers will see it and put the product liability stuff somewhere else where the lawyers can find it. For a microwave oven, there are probably about half a dozen real risks that people should know about. Several of them are relatively obvious (e.g., don't heat sealed containers) and some are not obvious (e.g., liquids heated in the microwave can become superheated and explode).

Maybe we'll get a handle on risk someday. In the meantime, inform your friends and children that they should be careful about heating liquids in the microwave, particularly in glass or glazed containers. Just knowing that superheating is possible would probably halve the number of burns and other injuries that result from superheating accidents.

Superheated water doesn't always wait until triggered before undergoing sudden boiling. All that's needed to start an explosion is for something to introduce an initial "seed" bubble into the liquid. Sometimes the container already has everything necessary to form a seed bubble and it's just a matter of getting the water hot enough to start that process. Many seed bubbles begin as trapped air in tiny crevices. As the water gets hotter, the size of any trapped air pocket grows and eventually it may be able to break free as a real seed bubble. When water is sufficiently superheated, just a single seed bubble is enough to start an explosion and empty the container completely. In your case, the coffee flash boiled spontaneously after something inside it nucleated the first bubble.

This sort of accident happens fairly often and we rarely think much about it as we sponge up the spilled liquid inside the microwave oven. But had your friend been unlucky enough to stop heating the coffee a second or two before that POP, she might have been injured while taking the coffee out of the oven. The moral of this story is to avoid overcooking any liquid in the microwave oven. If you must drink your coffee boiling hot, pay attention to it as it heats up so that it doesn't cook too long and then let it sit for a minute after the oven turns off. If you don't like your coffee boiling hot, then don't heat it to boiling at all.

I'm afraid that there's no easy answer to this question. You can use a microwave oven to superheat water in any container that doesn't assist bubble formation. How a particular container behaves is hard for me to say without experimenting. I'd heat a small amount of water (1/2 cup or less) in the container and look at it through the oven's window to see if the water boils nicely, with lots of steam bubbles streaming upward from many different points on the inner surface of the container. The more easily water boils in the container, the less likely it is to superheat when you cook it too long. (If you try this experiment, leave the potentially superheated water in the closed microwave oven to cool!)

Glass containers are clearly the most likely to superheat water because their surfaces are essentially perfect. Glasses have the characteristics of frozen liquids and a glass surface is as smooth as... well, glass. When you overheat water in a clean glass measuring cup, your chances of superheating it at least mildly are surprisingly high. The spontaneous bubbling that occurs when you add sugar, coffee powder, or a teabag to microwave-heated water is the result of such mild superheating. Fortunately, severe superheating is much less common because defects, dirt, or other impurities usually help the water boil before it becomes truly dangerous. That's why most of us avoid serious injuries.

However, even non-transparent microwaveable containers often have glass surfaces. Ceramics are "glazed," which means that they are coated with glass for both sealing and decoration. Many heavy mixing bowls are glass or glass-ceramics. As you can see, it's hard to get away from trouble. I simply don't know how plastic microwaveable containers behave when heating water; they may be safe or they may be dangerous.

If you're looking for a way out of this hazard, here are my suggestions. First, learn to know how long a given amount of liquid must be heated in your microwave in order to reach boiling and don't cook it that long. If you really need to boil water, be very careful with it after microwaving or boil it on a stovetop instead. My microwave oven has a "beverage" setting that senses how hot the water is getting. If the water isn't hot enough when that setting finishes, I add another 30 seconds and then test again. I never cook the water longer than I need to. Cooking water too long on a stovetop means that some of it boils away, but doing the same in a microwave oven may mean that it becomes dangerously superheated. Your children can still "cook" soup in the microwave if they use the right amount of time. Children don't like boiling hot soup anyway, so if you figure out how long it takes to heat their soup to eating temperature and have them cook their soup only that long, they'll never encounter superheating. As for dad's coffee water, same advice. If dad wants his coffee boiling hot, then he should probably make it himself. Boiling water is a hazard for children even without superheating.

Second, handle liquids that have been heated in a microwave oven with respect. Don't remove a liquid the instant the oven stops and then hover over it with your face exposed. If the water was bubbling spasmodically or not at all despite heavy heating, it may be superheated and deserves particular respect. But even if you see no indications of superheating, it takes no real effort to be careful. If you cooked the water long enough for it to reach boiling temperature, let it rest for a minute per cup before removing it from the microwave. Never put your face or body over the container and keep the container at a safe distance when you add things to it for the first time: powdered coffee, sugar, a teabag, or a spoon.

Finally, it would be great if some entrepreneurs came up with ways to avoid superheating altogether. The makers of glass containers don't seem to recognize the dangers of superheating in microwave ovens, despite the mounting evidence for the problem. Absent any efforts on their parts to make the containers intrinsically safer, it would be nice to have some items to help the water boil: reusable or disposable inserts that you could leave in the water as it cooked or an edible powder that you could add to the water before cooking. Chemists have used boiling chips to prevent superheating for decades and making sanitary, nontoxic boiling sticks for microwaves shouldn't be difficult. Similarly, it should be easy to find edible particles that would help the water boil. Activated carbon is one possibility.

Last night's report wasn't meant to scare you away from using your microwave oven or keep you from heating water in it. It was intended to show you that there is a potential hazard that you can avoid if you're informed about it. Microwave ovens are wonderful devices and they prepare food safely and efficiently as long as you use them properly. "Using them properly" means not heating liquids too long in smooth-walled containers.

Water doesn't always boil when it is heated above its normal boiling temperature (100 °C or 212 °F). The only thing that is certain is that above that temperature, a steam bubble that forms inside the body of the liquid will be able to withstand the crushing effects of atmospheric pressure. If no bubbles form, then boiling will simply remain a possibility, not a reality. Something has to trigger the formation of steam bubbles, a process known as "nucleation." If there is no nucleation of steam bubbles, there will be no boiling and therefore no effective limit to how hot the water can become.

Nucleation usually occurs at hot spots during stovetop cooking or at defects in the surfaces of cooking vessels. Glass containers have few or no such defects. When you cook water in a smooth glass container, using a microwave oven, it is quite possible that there will be no nucleation on the walls of the container and the water will superheat. This situation becomes even worse if the top surface of the water is "sealed" by a thin layer of oil or fat so that evaporation can't occur, either. Superheated water is extremely dangerous and people have been severely injured by such water. All it takes is some trigger to create the first bubble-a fork or spoon opening up the inner surface of the water or striking the bottom of the container-and an explosion follows. I recently filmed such explosions in my own microwave (low-quality movie (749KB), medium-quality movie (5.5MB)), or high-quality movie (16.2MB)). As you'll hear in my flustered remarks after "Experiment 13," I was a bit shaken up by the ferocity of the explosion I had triggered, despite every expectation that it would occur. After that surprise, you'll notice that I became much more concerned about yanking my hand out of the oven before the fork reached the water. I recommend against trying this dangerous experiment, but if you must, be extremely careful and don't superheat more than a few ounces of water. You can easily get burned or worse. For a reader's story about a burn he received from superheated water in a microwave, touch here.

Here is a sequence of images from the movie of my experiment, taken 1/30th of a second apart:

Yes, this sort of accident can and does happen. The water superheated and then boiled violently when disturbed. Here's how it works:

Water can always evaporate into dry air, but it normally only does so at its surface. When water molecules leave the surface faster than they return, the quantity of liquid water gradually diminishes. That's ordinary evaporation. However, when water is heated to its boiling temperature, it can begin to evaporate not only from its surface, but also from within. If a steam bubble forms inside the hot water, water molecules can evaporate into that steam bubble and make it grow larger and larger. The high temperature is necessary because the pressure inside the bubble depends on the temperature. At low temperature, the bubble pressure is too low and the surrounding atmospheric pressure smashes it. That's why boiling only occurs at or above water's boiling temperature. Since pressure is involved, boiling temperature depends on air pressure. At high altitude, boiling occurs at lower temperature than at sea level.

But pay attention to the phrase "If a steam bubble forms" in the previous paragraph. That's easier said than done. Forming the initial steam bubble into which water molecules can evaporate is a process known as "nucleation." It requires a good number of water molecules to spontaneously and simultaneously break apart from one another to form a gas. That's an extraordinarily rare event. Even in a cup of water many degrees above the boiling temperature, it might never happen. In reality, nucleation usually occurs at a defect in the cup or an impurity in the water—anything that can help those first few water molecules form the seed bubble. When you heat water on the stove, the hot spots at the bottom of the pot or defects in the pot bottom usually assist nucleation so that boiling occurs soon after the boiling temperature is reached. But when you heat pure water in a smooth cup using a microwave oven, there may be nothing present to help nucleation occur. The water can heat right past its boiling temperature without boiling. The water then superheats—its temperature rising above its boiling temperature. When you shake the cup or sprinkle something like sugar or salt into it, you initiate nucleation and the water then boils violently.

Fortunately, serious microwave superheating accidents are fairly unusual. However, they occur regularly and some of the worst victims require hospital treatment. I have heard of extreme cases in which people received serious eye injuries and third degree burns that required skin grafts and plastic surgery.

You can minimize the chance of this sort of problem by not overcooking water or any other liquid in the microwave oven, by waiting about 1 minute per cup for that liquid to cool before removing it from the microwave if there is any possibility that you have superheated it, and by being cautious when you first introduce utensils, powders, teabags, or otherwise disturb very hot liquid that has been cooked in a microwave oven. Keep the water away from your face and body until you're sure it's safe and don't ever hover over the top of the container. Finally, it's better to have the liquid boil violently while it's inside the microwave oven than when it's outside on your counter and can splatter all over you. Once you're pretty certain that the water is no longer superheated, you can ensure that it's safe by deliberately nucleating boiling before removing the cup from the microwave. Inserting a metal spoon or almost any food into the water should trigger boiling in superheated water. A pinch of sugar will do the trick, something I've often noticed when I heat tea in the microwave. However, don't mess around with large quantities of superheated water. If you have more than 1 cup of potentially superheated water, don't try to nucleate boiling until you've waited quite a while for it to cool down. I've been scalded by the stuff several times even when I was prepared for an explosion. It's really dangerous.

For a reader's story about a burn he received from superheated water in a microwave, touch here.

The relative stabilities of liquid and gaseous water depend on both temperature and pressure. To understand this, consider what is going on at the surface of a glass of water. Water molecules in the liquid water are leaving the water's surface to become gas above it and water molecules in the gas are landing and joining the liquid water below. It's like a busy airport, with lots of take-offs and landings. If the glass of water is sitting in an enclosed space, the arrangement will eventually reach equilibrium—the point at which there is no net transfer of molecules between the liquid in the glass and the gas above it. In that case, there will be enough water molecules in the gas to ensure that they land as often as they leave.

The leaving rate (the rate at which molecules break free from the liquid water) depends on the temperature. The hotter the water is, the more frequently water molecules will be able to break away from their buddies and float off into the gas. The landing rate (the rate at which molecules land on the water's surface and stick) depends on the density of molecules in the gas. The more dense the water vapor, the more frequently water molecules will bump into the liquid's surface and land.

As you raise the temperature of the water in your glass, the leaving rate increases and the equilibrium shifts toward higher vapor density and less liquid water. By the time you reach 100° Celsius, the equilibrium vapor pressure is atmospheric pressure, which is why water tends to boil at this temperature (it can form and sustain steam bubbles). Above this temperature the equilibrium vapor pressure exceeds atmospheric pressure. The liquid water and the gas above it can reach equilibrium, but only if you allow the pressure in your enclosed system to exceed atmospheric pressure. However, if you open up your enclosed system, the water vapor will spread out into the atmosphere as a whole and there will be a never-ending stream of gaseous water molecules leaving the glass. Above 100° C, liquid water can't exist in equilibrium with atmospheric pressure gas, even if that gas is pure water vapor.

So how can you superheat water? Don't wait for equilibrium! The road to equilibrium may be slow; it may take minutes or hours for the liquid water to evaporate away to nothing. In the meantime, the system will be out of equilibrium, but that's ok. It happens all the time: a snowman can't exist in equilibrium on a hot summer day, but that doesn't mean that you can't have a snowman at the beach... for a while. Superheated water isn't in equilibrium and, if you're patient, something will change. But in the short run, you can have strange arrangements like this without any problem.

The microwave oven is superheating the water to a temperature slightly above its boiling temperature. It can do this because it doesn't help water boil the way a normal coffee maker does. For water to boil, two things must occur. First, the water must reach or exceed its boiling temperature—the temperature at which a bubble of pure steam inside the water becomes sturdy enough to avoid being crushed by atmospheric pressure. Second, bubbles of pure steam must begin to nucleate inside the water. It's the latter requirement that's not being met in the water you're heating with the microwave. Steam bubbles rarely form of their own accord unless the water is far above its boiling temperature. That's because a pure nucleation event requires several water molecules to break free of their neighbors simultaneously to form a tiny steam bubble and that's very unlikely at water's boiling temperature. Instead, most steam bubbles form either at hot spots, or at impurities or imperfections—scratches in a metal pot, the edge of a sugar crystal, a piece of floating debris. When you heat clean water in a glass container using a microwave oven, there are no hot spots and almost no impurities or imperfections that would assist boiling. As a result, the water has trouble boiling. But as soon as you add a powder to the superheated water, you trigger the formation of steam bubbles and the liquid boils madly.

When you heated the water in the microwave oven, you raised its temperature above its boiling temperature, yet it did not boil. While the water was hot enough to boil—that is, any steam bubble that formed in this hot water would have a pressure at least equal to atmospheric pressure and would not be crushed by the surrounding air—the water was having a difficult time forming steam bubbles. For a bubble to appear, several water molecules must simultaneously break free of their neighbors to form a bubble nucleus. Once this nucleation has occurred, additional water molecules can evaporate into the bubble, making it grow. This nucleation is rare in pure water near its boiling temperature; in most cases it is assisted by hot spots at the bottom of a pot on the stove or by imperfections in the container holding the water. But when you heat water in a glass or glazed ceramic container in a microwave oven, there are no hot spots or surface imperfections to nucleate the bubbles. The water superheats above its boiling temperature. When you add sugar crystals to this superheated water, the crystal's sharp edges and points assist the nucleation of steam bubbles and the water boils violently.

Your suggestions for why the bubbles appear raise two interesting points. First, in a thermal system such as hot water, you can't identify some molecules as being boiling hot and others as being cooler—temperature is a property of the entire system and not of individual molecules. However, at a given instant, there are molecules with more energy than their neighbors and it is these energetic molecules that may break free of their neighbors to form a bubble nucleus.

Second, water often contains dissolved gases and these gases come out of solution when the water is heated. While many of the gas molecules leave through the water's surface, some of them may leave as bubbles from within the water. This gas bubble formation requires nucleation as well, which is why these bubbles often appear on the inner surfaces of a metal pot on the stove—flaws in the pot's surface assist bubble nucleation. But these gas bubbles aren't what you observed; there just isn't that much dissolve gas. You can prove that the bubbles you observe are steam: repeat the experiment several times with the same water. Each time you heat the water and add sugar, it bubbles wildly—something that wouldn't be possible if you were simply releasing dissolved gases from the water.