|MLA Citation:||Bloomfield, Louis A. "Water, Steam, and Ice Home Page" How Everything Works 21 Apr 2018. 21 Apr 2018 <http://www.howeverythingworks.org/prints.php?topic=water_steam_and_ice&page=0>.|
What you are actually seeing when raindrops land on warm surfaces is tiny water droplets in the air, a mist of condensation. Those droplets happen in a couple of steps. First, the surface warms a raindrop and speeds up its evaporation. Second, a small portion of warm, especially moist air rises upward from the evaporating raindrop. Third, that portion of warm moist air cools as it encounters air well above the warmed surface. The sudden drop in temperature causes the moist air to become supersaturated with moistureit now contains more water vapor than it can retain at equilibrium. The excess moisture condenses to form tiny water droplets that you see as a mist.
This effect is particularly noticeable when it's raining because the humidity in the air is already very near 100%. The extra humidity added when the warmed raindrops evaporate is able to remain gaseous only in warmed air. Once that air cools back to the ambient temperature, the moisture must condense back out of it, producing the mist.
That lower-density objects float on water is a consequence of Archimedes' principle: when an object displaces a fluid, it experiences an upward buoyant force equal in amount to the weight of the displaced fluid. If you submerge a piece of ice completely in water, that piece of ice will experience an upward buoyant force that exceeds the ice's weight because the water it displaces weighs more than the ice itself. The ice then experiences two forces: its downward weight and the upward buoyant force from the water. Since the upward force is stronger than the downward force, the ice accelerates upward. It rises to the surface of the water, bobs up and down a couple of times, and then settles at equilibrium.
At that equilibrium, the ice is displacing a mixture of water and air. Amazingly enough, that mixture weighs exactly as much as the ice itself, so the ice now experiences zero net force. That's why its at equilibrium and why it can remain stationary. It has settled at just the right height to displace its weight in water and air.
As for why ice is less dense than water, that has to do with the crystal structure of solid ice and the more complicated structure of liquid water. Ice's crystal structure is unusually spacious and it gives the ice crystals their surprisingly low density. Water's structure is more compact and dense. This arrangement, with solid water less dense than liquid water, is almost unique in nature. Most solids are denser than their liquids, so that they sink in their liquids.
If the temperature of overly moist air is 32 F or below, planes preparing for takeoff can accumulate heavy burdens of ice. When water vapor condenses as ice directly onto the wings themselves, that condensation process is called deposition and is familiar to you as frost. Deposition is a relatively slow process, so most of the trouble for planes occurs when it is actually snowing or sleeting. Removing the ice then requires either heat or chemicals.
When the plane is flying at high altitudes, however, the air is extremely dry. Even though the air temperature is far below the freezing temperature of water, the fraction of water molecules in the air is nearly zero and the relative humidity is much less than 100%. That means that an ice cube suspended in that dry air would actually evaporate away to nothing. Technically, that "evaporation" of ice directly into water vapor is call sublimation and you've seen it before. Think of all the foods that have experienced freezer burn in your frost-free (i.e., extremely dry air) refrigerator or the snow that has mysteriously disappeared from the ground during a dry spell even though the temperature has never risen above freezing. Both are cases of sublimation where water molecules left the ice to become moisture in the air.
Part of the reason why it takes so long for the dissolved gases to come out of solution is that the gas can only leave through the exposed surface of the liquid. In an open bottle of carbonated beverage that may be only a few square inches or a few dozen square centimeters. The dissolved gas has to find its way to that exposed surface and break free of the liquid. That's a slow process. The same thing is happening in your wine: the dissolve carbon dioxide and oxygen gases must normally find their way to the top of the tank and then break free to enter the gaseous region at the top of the tank another slow processes. To speed the escape of dissolved gases, you can enlarge the exposed surface of the liquid by bubbling an inert gas through the liquid. Here, inert gas is any gas that doesn't dissolve significantly in the liquid and that doesn't affect the liquid if it does dissolve. Nitrogen is great for wine because it doesn't interact chemically with the wine. As you let bubbles of nitrogen float upward through the wine, you provide exposed surface within the body of the liquid wine and allow carbon dioxide and oxygen to break free of the liquid and enter those bubbles.
The spherical interface between the gas bubble and the surrounding liquid is a busy, active place gas molecules are moving between the gas and liquid in both directions. Because carbon dioxide is over-concentrated in the liquid, it is statistically more likely for a carbon dioxide molecule to leave the liquid and enter the bubble's gas than the other way around. It takes a little energy to break those carbon dioxide molecules free of the liquid and that need for energy affects the balance between dissolved carbon dioxide and gaseous carbon dioxide at equilibrium. The harder it is for the carbon dioxide molecules to obtain the energy they need to escape from the liquid, the greater the equilibrium concentration of dissolved carbon dioxide the saturated concentration. But your wine is supersaturated, containing more than the equilibrium concentration of dissolved carbon dioxide, so carbon dioxide molecules go from liquid to gas more often than the other way around.
When the degree of supersaturation (excess gas concentration) is high, the transfer of gas molecules from liquid to gas bubble can be fast enough to make the bubbles grow in size significantly as they float up through the wine. You can see this type of rapid bubble growth in a glass of freshly poured soda, beer, or champagne. In beer, champagne, and your wine, however, the liquid surface of the bubble contains various natural chemicals that alter the interface with the gas and affect bubble growth. The "tiny bubbles" of good champagne reflect that influence.
Another way to provide the extra exposed surface in the wine and thereby allow the supersaturated dissolved gases to come out of solution would be to agitate the wine so violently that empty cavities open up within the wine. Although that approach would provide lots of extra surface, it would probably not be good for the wine. Bubbling gas through the wine is a much more gentle.
The exact choice of gas barely matters as long as it is chemically inert in the wine. Argon or helium would be just as effective, but they're more expensive (and in the case of helium, precious). The temperature of the gas doesn't matter significantly, but the temperature of the wine does. The cooler the wine, the higher the concentration of dissolved carbon dioxide and oxygen it will contain at equilibrium so you'll remove more of those gases if you do your bubbling while the wine is relatively warm.
The explanation is both simple and interesting: the rate at which water molecules leave the cloths doesn't depend on whether the window is open or closed, but the rate at which water molecules return to the cloths certainly does. That return rate depends on the air's moisture content and can range from zero in dry air to extremely fast in damp air. Air's moisture content is usually characterized by its relative humidity, with 100% relative humidity meaning that air's water molecules land on surfaces exactly as fast as water molecules in liquid water leave its surface. When you expose a glass of water to air at 100% relative humidity, the glass will neither lose nor gain water molecules because the rates at which water molecules leave the water and land on the water are equal. Below 100% relative humidity, the glass will gradually empty due to evaporation because leaving will outpace landing. Above 100% relative humidity, the glass will gradually fill due to condensation because landing will outpace leaving.
The same story holds true for wet clothes. The higher the air's relative humidity, the harder it becomes for water to evaporate from the cloths. Landing is just too frequent in the humid air. At 100% relative humidity the clothes won't dry at all, and above 100% relative humidity they'll actually become damper with time.
When you dry clothes in a room with the window open and the relative humidity of the outdoor air is less than 100%, water molecules will leave the clothes more often than they'll return, so the clothes will dry. But when the window is closed, the leaving water molecules will remain trapped in the room and will gradually increase the room air's relative humidity. The drying process will slow down as the water-molecule return rate increases. When the room air's relative humidity reaches 100%, drying will cease altogether.
Since the freezer has a nearly airtight seal, the air it contains remains inside it for a long time. That means that the odor molecules that occasionally break free of a pungent casserole at one end of the freezer have every opportunity to land on and stick to an ice cube at the other end. With time, the ice cube acquires the scent of the casserole and becomes unappealing.
To stop this migration of molecules, you should seal each item in the freezer in its own container. That way, any molecules that leave the food's surface will eventually return to it. Since ice cubes are normally exposed to the air in the freezer, keeping the odor molecules trapped in their own sealed containers keeps the freezer air fresh and the ice cubes odor-free.
In actually, some of the water molecules have almost certainly left via a form of solid-to-gas evaporation known technically as "sublimation." You have seen this conversion of ice into gas when you have noticed that old ice cubes in your freezer are smaller than they used to be or when you see that the snow outside during a cold spell seems to vanish gradually without ever melting. Sublimation is also the cause of "freezer burn" for frozen foods left without proper wrapping.
By giving the sealed bottle a shake, your mother-in-law is simply speeding up the approach to equilibrium. She is helping the CO2 molecules leave the beverage and enter the gas phase. The bottle then pressurizes faster, but at the expense of dissolved molecules in the beverage itself. If there is any chance that you'll drink more before equilibrium has been reached, you do best not to shake the bottle. That way, the equilibration process will be delayed as much as possible and you may still be able to drink a few more of those CO2 molecules rather than breathing them.
Incidentally, shaking a new bottle of soda just before you open it also speeds up the equilibration process. For an open bottle, equilibrium is reached when essentially all the CO2 molecules have left and are in the gas phase (since the gas phase extends over the whole atmosphere). That's not what you want at all. Instead, you try not to shake the beverage so that it stays away from equilibrium (and flatness) as long as possible. For most opened beverages, equilibrium is not a tasty situation.
The leaving rate (the rate at which molecules break free from the liquid water) depends on the temperature. The hotter the water is, the more frequently water molecules will be able to break away from their buddies and float off into the gas. The landing rate (the rate at which molecules land on the water's surface and stick) depends on the density of molecules in the gas. The more dense the water vapor, the more frequently water molecules will bump into the liquid's surface and land.
As you raise the temperature of the water in your glass, the leaving rate increases and the equilibrium shifts toward higher vapor density and less liquid water. By the time you reach 100° Celsius, the equilibrium vapor pressure is atmospheric pressure, which is why water tends to boil at this temperature (it can form and sustain steam bubbles). Above this temperature the equilibrium vapor pressure exceeds atmospheric pressure. The liquid water and the gas above it can reach equilibrium, but only if you allow the pressure in your enclosed system to exceed atmospheric pressure. However, if you open up your enclosed system, the water vapor will spread out into the atmosphere as a whole and there will be a never-ending stream of gaseous water molecules leaving the glass. Above 100° C, liquid water can't exist in equilibrium with atmospheric pressure gas, even if that gas is pure water vapor.
So how can you superheat water? Don't wait for equilibrium! The road to equilibrium may be slow; it may take minutes or hours for the liquid water to evaporate away to nothing. In the meantime, the system will be out of equilibrium, but that's ok. It happens all the time: a snowman can't exist in equilibrium on a hot summer day, but that doesn't mean that you can't have a snowman at the beach... for a while. Superheated water isn't in equilibrium and, if you're patient, something will change. But in the short run, you can have strange arrangements like this without any problem.
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