|MLA Citation:||Bloomfield, Louis A. "Question 971"|
How Everything Works 20 Apr 2018. 20 Apr 2018 <http://howeverythingworks.org/print1.php?QNum=971>.
Argon and nitrogen are chemically inert, so that the tungsten filament can't burn in the argon and nitrogen, and each argon atom or nitrogen molecule is massive enough that when a tungsten atom that's trying to leave the filament hits it, that tungsten atom may rebound back onto the filament. The argon and nitrogen gases thus prolong the life of the filament. Unfortunately, these gases also convey heat away from the filament via convection. You can see evidence of this convection as a dark spot of tungsten atoms that accumulate at the top of the bulb. That black smudge consists of tungsten atoms that didn't return to the filament and were swept upward as the hot argon and nitrogen gases rose.
However, some premium light bulbs contain krypton gas rather than argon gas. Like argon, krypton is chemically inert. But a krypton atom is more massive than an argon atom, making it more effective at bouncing tungsten atoms back toward the filament after they sublime. Krypton gas is also a poorer conductor of heat than argon gas, so that it allows the filament to convert its power more efficiently into visible light. Unfortunately, krypton is a rare constituent of our atmosphere and very expensive. That's why it's only used in premium light bulbs, together with some nitrogen gas.
Incidentally, the filament in many incandescent bulbs is treated with a small amount of a phosphorus-based "getter" that reacts with any residual oxygen that may be in the bulb the first time the filament becomes hot. That's how the manufacturer ensures that there will be no oxygen in the bulb for the tungsten filament to react with.