|MLA Citation:||Bloomfield, Louis A. "Question 680"|
How Everything Works 16 Jan 2018. 16 Jan 2018 <http://howeverythingworks.org/print1.php?QNum=680>.
Unfortunately, the two solid electrodes in a NiCad battery are damaged by repeated charging and discharging. These electrodes work best when they are both fine powders (the positive electrode is nickel hydroxide powder and the negative electrode is cadmium metal powder). With repeated use, the powder particles grow larger and larger and they stop contributing to the battery's power. "Memory" appears during the discharge cycle when all the useful small particles have been used up and only the undesirable large particles remain. Repeated charging and partial discharging tends to convert many of the small particles into large particles. You can improve the battery by fully discharging it before recharging it, presumably because this deep discharge breaks up the larger particles so that the battery contains mostly small particles once again.