|MLA Citation:||Bloomfield, Louis A. "Question 1589: Why does water change from liquid to gas at temperatures below 212 F?"|
How Everything Works 25 May 2018. 25 May 2018 <http://howeverythingworks.org/print1.php?QNum=1589>.
What you are actually seeing when raindrops land on warm surfaces is tiny water droplets in the air, a mist of condensation. Those droplets happen in a couple of steps. First, the surface warms a raindrop and speeds up its evaporation. Second, a small portion of warm, especially moist air rises upward from the evaporating raindrop. Third, that portion of warm moist air cools as it encounters air well above the warmed surface. The sudden drop in temperature causes the moist air to become supersaturated with moisture—it now contains more water vapor than it can retain at equilibrium. The excess moisture condenses to form tiny water droplets that you see as a mist.
This effect is particularly noticeable when it's raining because the humidity in the air is already very near 100%. The extra humidity added when the warmed raindrops evaporate is able to remain gaseous only in warmed air. Once that air cools back to the ambient temperature, the moisture must condense back out of it, producing the mist.