|MLA Citation:||Bloomfield, Louis A. "Question 1442"|
How Everything Works 25 May 2018. 25 May 2018 <http://howeverythingworks.org/print1.php?QNum=1442>.
To see why this arrangement is stable, consider what would happen if something tried to upset it. For example, what would happen if this mixture were to begin losing heat to its surroundings? Its temperature would begin to drop but then the water would begin to freeze and release thermal energy: when water molecules stick together, they release chemical potential energy as thermal energy. This thermal energy release would raise the temperature back to 32 F. The bath thus resists attempts at lowering its temperature.
Similarly, what would happen if the mixture were to begin gaining heat from its surroundings? Its temperature would begin to rise but then the ice would begin to melt and absorb thermal energy: separating water molecules increases their chemical potential energy and requires an input of thermal energy. This lost thermal energy would lower the temperature back to 32 F. The bath thus resists attempts at raising its temperature.
So an ice/water bath self-regulates its temperature at 32 F. The only other quantities affecting this temperature are the air pressure (the bath temperature could shift upward by about 0.003 degrees F during the low pressure of a hurricane) and dissolved chemicals (half an ounce of table salt per liter of bath water will shift the bath temperature downward by about 1 degree F).