|MLA Citation:||Bloomfield, Louis A. "Question 1429"|
How Everything Works 22 Oct 2017. 22 Oct 2017 <http://howeverythingworks.org/print1.php?QNum=1429>.
That is what happens when you carefully weave a needle into a latex balloon—the needle separates the polymer strands locally, but doesn't actually pull them apart or break them. Since breaking the latex molecules will probably cause the balloon to tear and burst, you have to be very patient and use a very sharp needle. I usually oil the needle before I do this and I don't try to insert the needle in the most highly stressed parts of the balloon. The regions near the tip of the balloon and near where it is filled are the least stressed and thus the easiest to pierce successfully with a needle. A reader has informed me that coating the needle with Vasoline is particularly helpful.
One final note: a reader pointed out that it is also possible to put a needle through a balloon with the help of a small piece of adhesive tape. If you put the tape on a patch of the inflated balloon, it will prevent the balloon from ripping when you pierce the balloon right through the tape. This "cheaters" approach is more reliable than trying to thread the needle between the latex molecules, but it's less satisfying as well. But it does point out the fact that a balloon bursts because of tearing and that if you prevent the balloon from tearing, you can pierce it as much as you like.