|MLA Citation:||Bloomfield, Louis A. "Question 1428"|
How Everything Works 20 May 2018. 20 May 2018 <http://howeverythingworks.org/print1.php?QNum=1428>.
When the unit is operating and pumping heat, the evaporator becomes cold and the condenser becomes hot. A fan blows warm, moist air from the room through the evaporator coils and that air's temperature drops. This temperature drop changes the behavior of water molecules in the air. When the air and its surroundings were warm, any water molecule that accidentally bumped into a surface could easily return to the air. Thus while water molecules were always landing on surfaces or taking off, the balance was in favor of being in the air. But once the air and its surroundings become cold, any water molecules that bump into a surface tend to stay there. Water molecules are still landing on surfaces and taking off, but the balance is in favor of staying on the surface as either liquid water or solid ice. That's why dew or frost form when warm moist air encounters cold ground. In the dehumidifier, much of the air's water ends up dripping down the coils of the evaporator into a collection basin.
All that remains is for the dehumidifier to rewarm the air. It does this by passing the air through the condenser coils. The thermal energy that was removed from the air by the evaporator is returned to it by the condenser. In fact, the air emerges slightly hotter than before, in part because it now contains all of the energy used to operate the dehumidifier and in part because condensing moisture into water releases energy. So the dehumidifier is using temperature changes to separate water and air.