|MLA Citation:||Bloomfield, Louis A. "Question 1256"|
How Everything Works 25 May 2018. 25 May 2018 <http://howeverythingworks.org/print1.php?QNum=1256>.
Each hemoglobin molecule contains four heme groups, the iron-containing structures that actually form the reversible bond with oxygen molecules and that also give the hemoglobin its color. However, this color depends on the oxidization state of the heme group—red when the heme group is binding oxygen and blue-purple when the heme group is alone. That color difference explains why someone who is holding their breath may "turn blue"—their hemoglobin is lacking in oxygen. The clip you wore was analyzing the color of your blood to determine the extent of oxygenation in its hemoglobin. It measured your pulse rate by looking for periodic fluctuations in the opacity of your finger, brought on by changes in your finger's blood content with each heartbeat.