How Everything Works
How Everything Works How Everything Works

Question 1483

My mother-in-law feels that by shaking a partially consumed bottle of carbonated beverage after re-sealing it, it will re-pressurize keeping the carbonation better than just resealing it. I believe that, since the amount of CO2 in the beverage and the container will stay constant, that either re-sealing or re-sealing and shaking will have the same net effect when it comes to maintaining carbonation. Is she right? - JK, New Mexico
No, you are right. In the long run, the number of CO2 molecules left in the bottle when you close it is all that matters. Those molecules will drift in and out of the liquid and gas phases until they reach equilibrium. At the equilibrium point, there will be enough molecules in the gas phase to pressurize the bottle and enough in the liquid phase to give the beverage a reasonable amount of bite.

By giving the sealed bottle a shake, your mother-in-law is simply speeding up the approach to equilibrium. She is helping the CO2 molecules leave the beverage and enter the gas phase. The bottle then pressurizes faster, but at the expense of dissolved molecules in the beverage itself. If there is any chance that you'll drink more before equilibrium has been reached, you do best not to shake the bottle. That way, the equilibration process will be delayed as much as possible and you may still be able to drink a few more of those CO2 molecules rather than breathing them.

Incidentally, shaking a new bottle of soda just before you open it also speeds up the equilibration process. For an open bottle, equilibrium is reached when essentially all the CO2 molecules have left and are in the gas phase (since the gas phase extends over the whole atmosphere). That's not what you want at all. Instead, you try not to shake the beverage so that it stays away from equilibrium (and flatness) as long as possible. For most opened beverages, equilibrium is not a tasty situation.


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